Modeling the Diffusion Effects through the Iron Carbonate Layer in the Carbon Dioxide Corrosion of Carbon Steel

نویسندگان

  • S. RAJAPPA
  • R. ZHANG
چکیده

A mechanistic model was developed for predicting carbon dioxide corrosion rates of carbon steel pipes in multiphase flow conditions. The model incorporates the chemistry, thermodynamics of carbon dioxide dissolution, multiphase mass transfer, electrochemical kinetics on the metal surface and the presence of a corrosion product film. The predicted corrosion rates show good agreement with the experimental results.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

A Mechanistic Model for Carbon Dioxide Corrosion of Mild Steel in the Presence of Protective Iron Carbonate Films—Part 1: Theory and Verification

A mechanistic model of uniform carbon dioxide (CO2) corrosion is presented that covers the following: electrochemical reactions at the steel surface, diffusion of species between the metal surface and the bulk including diffusion through porous surface films, migration due to establishment of potential gradients, and homogenous chemical reactions including precipitation of surface films. The mo...

متن کامل

The Effect of Time on the Formation & Growth of Passive Layer on Carbon Steel A516 Gr. 70 in Sour Water

A proposed method for protecting carbon steel and hence reducing iron release in an aqueous solution saturated with H2S is presented in this paper. The method is based on forming a stable and resistant sulfide layer (pyrite, FeS2, or pyrrhotite, Fe(1-x)S, phase or a mixture of both) on the carbon steel surface. The study on the formation of the sulfide layer was...

متن کامل

A Mechanistic Model for Carbon Dioxide Corrosion of Mild Steel in the Presence of Protective Iron Carbonate Films—Part 2: A Numerical Experiment

A theoretical carbon dioxide (CO2) corrosion model was used to conduct numerical experiments, which allowed total insight into the underlying physicochemical processes. The focus was on factors influencing protective iron carbonate film formation and the effect that these films have on the CO2 corrosion process. It was confirmed that high bulk pH, high temperature, high partial pressure of CO2,...

متن کامل

Basics Revisited: Kinetics of Iron Carbonate Scale Precipitation in Co2 Corrosion

Glass cell experiments were conducted to understand kinetics of iron carbonate scale formation in pure carbon dioxide (CO2) corrosion of mild steel. Weight gain and loss (WGL) method was used as a direct approach to investigate kinetics of scale formation. The experiments were done at the temperatures of 60C to 90C, and an iron carbonate supersaturation range of 12 to 350. It is found that the ...

متن کامل

Corrosion Inhibition of Carbon Steel in SULFIRAN® Process

In this investigation, attempts were directed to study the inhibitive effects of nitrite and phosphate base inhibitors for the carbon steel alloy samples, which are used in an acid gas treatment process (The SULFIRAN® solution), in Fe-EDTA solution. Electrochemical techniques, i.e. polarization curves and electrochemical impedance spectroscopy (EIS), were used to evaluate the inhibition efficie...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 1998